Currently working on a guide, here's the start of it. Enjoy.
::Bilbo's Buttons::
Stained Button: if you come in through the mountain's throat entrance...continue straight. You will come to a place where you can either go down, left, or right. Go right and follow the curve around. You will see a debris pile at the very end...loot it, the button is here.
Bent Button, Tarnished Button, and Blackened Cufflink: all random drops from goblins
Scratched Button: This is found near the named mob Narash. He is in a room off the blogmal tunnels. The button is in a battered chest. (War Steadings)
Shiny Button: This is found near Dagal the Observer. It is in his room inside a discarded pouch. (War Steadings)
Broken Cufflink: this can be found in a ruined bag in a tunnel near the Goblin King instance. (Eglanur)
Polished Button: I found this in Thundergrot. If you take the stairs to the very very bottom, and then follow the tunnels to the left...then take another immediate left...it is in a refuse pile near two lashers.